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I have read that this feature is only available per blog, not per user. So maybe this question is a feature request.
One data that I want send to you is the response to this question from the official facebook plugin. mjjojo says that is possible: http://wordpress.org/support/topic/automatic-post-to-user-facebook-wall?replies=2#post-4462719
Can I configure the automatic post to the user facebook wall?
Thanks!